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November 23, 2024

According to Decree 280-2024 published on February 28, 2024, in the Gazette officielle du Québec, the amendment to the Appendix 1 of the Regulation respecting occupational health and safety (RSST, RLRQ, c. S-2.1, r. 13) will come into force on March 14, 2024. These regulatory changes have not yet been incorporated into the current Substance Data Sheets of the Sampling Guide for Air Contaminants in the Workplace. An update is currently underway and will be available as soon as possible. Consequently, the information contained in the data sheets of substances modified or added in Decree 280-2024 is partially inaccurate or incomplete. Please consult our infoLABO (in French only) for more details. Please contact our client service: [email protected] for further information.

Pentaborane  

French name in the regulation: Pentaborane
CAS : 19624-22-7

Exposure Standards in RROHS regulation

Permissible exposure values (PEV)
ppm mg/m3 f/cc Notes
TWAEV 0,005 0,013 - -
STEV 0,015 0,039 - -
Ceiling - - - -
Carcinogenicity Sensitizer
Simple asphyxiantPercutaneous
Prohibited useProhibited recirculation
Minimum exposureExplosion hazard
Ototoxic

TWA adjustment for unusual work schedules

II : Daily adjustment

CNESST – Toxicological Index Service

Consult REPTOX file: Pentaborane

Analysis:

Pentaborane

Recommended method by the IRSST:
Method: OSHA - ID125G

Sampling protocol

Sampling device: Glass fritted tip impinger containing deionized water
Parameters:
Flow rate: 1 L/min
TWA sampling volume: 480 L
STEL sampling volume: 15 L
Remarks: This substance is not analyzed by our laboratories. It might be possible that the analysis be performed by another laboratory. Please contact the IRSST before sampling.

Principle: Inductively coupled plasma-optical emission spectrometer (ICP-OES)
Remarks: OSHA method ID-125G is for metallic elements and compounds and can be adapted to pentaborane. The device and the parameters on OSHA data sheet IMIS1986 are used.

OSHA Analytical Methods Manual, Method ID125G.: Metal particulates in workplace atmospheres (ICP analysis), 2002.