IRSST - Institut de recherche Robert-Sauvé en santé et en sécurité du travail

According to Decree 280-2024 published on February 28, 2024, in the Gazette officielle du Québec, the amendment to the Appendix 1 of the Regulation respecting occupational health and safety (RSST, RLRQ, c. S-2.1, r. 13) will come into force on March 14, 2024. These regulatory changes have not yet been incorporated into the current Substance Data Sheets of the Sampling Guide for Air Contaminants in the Workplace. An update is currently underway and will be available as soon as possible. Consequently, the information contained in the data sheets of substances modified or added in Decree 280-2024 is partially inaccurate or incomplete. Please consult our infoLABO (in French only) for more details. Please contact our client service: [email protected] for further information.

Germanium tetrahydride  

French name in the regulation: Germanium, tétrahydrure de
CAS : 7782-65-2

Exposure Standards in RROHS regulation

Permissible exposure values (PEV)
ppm mg/m3 f/cc Notes
TWAEV 0,2 0,63 - -
STEV - - - -
Ceiling - - - -
Carcinogenicity Sensitizer
Simple asphyxiantPercutaneous
Prohibited useProhibited recirculation
Minimum exposureExplosion hazard
Ototoxic

TWA adjustment for unusual work schedules

II : Daily adjustment

CNESST – Toxicological Index Service

Consult REPTOX file: Germanium tetrahydride

Analysis:

Germanium, tétrahydrure de

Recommended method by the IRSST:
Method: OSHA - IMIS1360
Sampling device: Activated charcoal tube 100/50 mg
Parameters:
Flow rate: 0,2 L/min
TWA sampling volume: 48 L
STEL sampling volume: -
Remarks: A mixed cellulose ester filter can be considered preceding the activated charcoal tube to eliminate the germanium compounds present as aerosol. Contact the IRSST before sampling.
Principle: Electrothermal atomic absorption spectrophotometry (ET-AAS)
OSHA, Chemical Information Manual. IMIS1360: Germanium Tetrahydride, 1993.